An EFTEM/HRTEM high-resolution study of the near surface of labradorite feldspar altered at acid pH: evidence for interfacial dissolution-reprecipitation   总被引：1，自引：0，他引：1  

R. Hellmann  J.-M. Penisson  R. L. Hervig  J.-H. Thomassin  M.-F. Abrioux 《Physics and Chemistry of Minerals》2003,30(4):192-197

Using an approach combining high-resolution and energy-filtered transmission electron microscopy (HRTEM and EFTEM), we have studied with Å to nm-spatial resolution the interfacial region that delimits the near-surface altered zone and non-altered labradorite feldspar after dissolution under acid pH conditions. The interface is characterized by extremely sharp and spatially coincident changes in structure and chemistry. The 500-nm-thick altered zone is depleted in interstitial cations (Ca, Na, K) and Al, a framework element, whereas it is enriched in H, O, and Si. Modeling H⁺-alkali interdiffusion within a 500-nm-thick altered zone shows that volume interdiffusion cannot reproduce the sharp chemical interfaces measured by EFTEM. Based on these new data, we propose that the near-surface altered zone is a result of interfacial dissolution-reprecipitation, and not of preferential leaching of cations and interdiffusion with H⁺. This implies an intrinsic dissolution process that is stoichiometric, where the breaking of bonds and release of interstitial cations and framework elements (Al, Si, and O) to solution occur contemporaneously at equal relative rates from the original fluid–mineral interface.  相似文献   

模拟扰动条件下太湖表层沉积物磷行为的研究   总被引：75，自引：8，他引：75  

张路  范成新  秦伯强  杨龙元 《湖泊科学》2001,13(1):35-42

利用恒温震荡器构筑的模拟扰动环境，研究了太湖水－沉积物界的磷释放和吸附行为。结果表明：表层沉积物的磷酸盐释放作用在模拟扰动条件下并不十分明显，在低强度的扰动条件下未观察到释放现象，模拟高强度扰动后，出现一个相对较强的释放过程，最大释放时沉积物上覆水浓度约为低强度扰动时的3倍，最大释放时间（Tmax)可能受磷酸盐形态分布的不同而有所差异，相比较而言，磷酸盐的吸附作用表现得十分明显迅速，沉积物上覆水磷酸盐浓度在0．5h后分别0229mg/L和l0.215mg／L下降为0．05mg/L和0.013mg/L，可以看出当上覆水磷酸盐浓度较高时，吸附作用的强度远大于释放作用，在25℃，模拟中等强度（100rpm)的模拟扰动条件下，当初始磷酸盐浓度为1．01mg/L时，梅梁湾和五里湖的表层沉积物吸附容量分别为每克千重吸附0．04mg和0.050mg磷酸盐，这种较高的吸附能力对浅水湖泊的磷酸盐缓冲作用能起到积极作用。  相似文献   

Auswirkungen des Ablassens von Hochwasserrückhaltebecken auf deren Limnochemie und Phytoplankton-Biozönose     

Susanne Maier  Klaus Zintz  Jürgen Bhmer  Petra Sterk  Hinrich Rahmann 《Limnologica》2001,31(3):239

Reservoirs have to be released when repairing of the dams is necessary. In 1995, two reservoirs in Baden-Württemberg (Germany) of similar age and volume (Lake Herrenbach near Göppingen, 1.0 Mio. m³ and Lake Breitenau near Heilbronn, 2.3 Mio. m³) were emptied. This allowed the singular possibility to investigate the effects of drainage and refilling on the limnochemistry and the phytoplankton biocoenosis of such artificial lakes.Before the drainage of the reservoirs, both lakes showed phosphorus release from the sediment during summer stagnation. Phosphorus values of Lake Herrenbach were regularly higher than those of Lake Breitenau (Lake Herrenbach 88 μg/l, Lake Breitenau 33 μg/l). During release, both lakes indicated higher phosphorus and chlorophyll concentrations as well as rising biomasses. Remarkable differences were observed during refilling of the reservoirs: while Lake Herrenbach showed higher transparency and lower phosphorus concentrations, Lake Breitenau progressed towards eutrophication (total phosphorus during summer 1996: Lake Herrenbach 30 μg/l, Lake Breitenau 55 μg/l). One reason for the reaction of Lake Breitenau was the reduced ground drainage during the refilling, which caused an accumulation of nutrients in the hypolimnion. Another reason was the mineralisation of vegetation which covered great parts of the dry lake sediment. The limnological change of Lake Herrenbach was not as clear but could be caused by the restauration of the pre-reservoir which was drainaged and dredged before the emptying of the main reservoir started as well as many other facts which differed Lake Herrenbach from Lake Breitenau.  相似文献   

Application of stress release models to historical earthquakes from North China   总被引：5，自引：0，他引：5  

Xiao-Gu Zheng  David Vere-Jones 《Pure and Applied Geophysics》1991,135(4):559-576

Univariate and multivariate stress release models are fitted to historical earthquake data from North China. It is shown that a better fit is obtained by treating separately the Eastern part of the region, including the North China Plain and Bohai Sea, and the Western part of the region, including the Ordos Plateau and its Eastern boundary. Further improvement is obtained by fitting the large events (M7.6) and smaller events in the Western region by different stress release models. The comparisons are made by computing the likelihoods of the fitted models and discounting the number of parameters used by Akaike's AIC criterion. The models are used to develop long-term risk scenarios for the East and West regions.  相似文献   

板内与板间地震活动时空分布的多重分形特征研究          下载免费PDF全文

陈时军  孙龙梅  马丽 《地震学报》2007,29(1):38-47

利用多重分形分析方法，考察了中国大陆和台湾地区以及新西兰的地震活动广义应变释放时间和空间分布的多重分形特征. 结果表明，地震活动时空分布的多重分形特征与不同地球动力学环境关系密切. 强震活动时间分布在板间地区具有比板内地区更明显的丛集性， 对中小地震这种丛集性差异较小；强震活动空间分布在板内地区具有比板间地区更强的丛集性，但对中小地震则相反.   相似文献   

Roles of Mesoscale Terrain and Latent Heat Release in Typhoon Precipitation： A Numerical Case Study     

李昀英  黄伟  赵焦枝 《大气科学进展》2007,24(1):35-43

The mesoscale orographic effects on typhoon Aere＇s precipitation are simulated using an Advanced Regional Eta-coordinate Model （AREM） version 3.0. In particular, the effects of the latent heat release are studied by two comparable experiments： with and without condensational heating. The results show that the typhoon rainfall is tripled by the southeastern China mesoscale terrain, and the condensational heating is responsible for at least half of the increase. One role of the latent heat release is to warm the atmosphere, leading to a depression of the surface pressure, which then causes a larger pressure difference in the zonal direction. This pressure gradient guides the water vapour to flow into the foothills, which in turn amplifies the water vapour flux divergence amplified, causing the typhoon rainfall to increase eventually. The other role of the latent heat release is to make the convection more organized, resulting in a relatively smaller rain area and stronger precipitation.  相似文献   

科尔沁沙地30种植物叶凋落物CO₂释放量及释放速率的研究     

孟庆涛  李玉霖  赵学勇  李玉强  赵玉萍 《中国沙漠》2007,27(6):960-967

 采用可以有效控制环境因子的室内土壤培养试验，初步研究了科尔沁沙地30种植物叶凋落物的CO₂释放量及释放速率。结果表明：①在28 d培养期内，不同植物叶凋落物释放的CO₂量差异很大，其中，多年生植物叶凋落物CO₂释放量平均值大于一年生植物，但二者之间的差异不显著；禾本科植物叶凋落物CO₂释放量平均值明显小于其他植物，二者之间呈显著差异。②在28 d培养期内，不同植物叶凋落物每四天CO₂释放速率差异很大。一年生与多年生植物叶凋落物28 d内每四天释放CO₂的速率无显著差异；禾本科与其他植物叶凋落物每四天释放CO₂的速率在培养的前16 d差异呈显著，而后差异消失。③植物叶凋落物的全碳含量，氮含量，C／N，灰分/N及灰分含量不同造成CO₂释放量及释放速率的差异。叶凋落物28 d释放CO₂的量与叶凋落物初始碳含量及灰分含量均无相关关系，与叶凋落物初始氮含量呈显著正相关，与叶凋落物C／N及灰分／N呈显著负相关。叶凋落物培养期内每四天释放CO₂的速率与叶凋落物初始碳含量无相关关系；叶凋落物0\_20天释放CO₂的速率与叶凋落物初始氮含量呈显著正相关，与叶凋落物C／N呈显著负相关；叶凋落物9\_28天CO₂释放速率与灰分／N呈显著负相关；培养后期（17\_28天）的CO₂释放速率与灰分含量呈显著负相关。  相似文献   

古新世—始新世最热事件对地球表层循环的影响及其触发机制   总被引：1，自引：0，他引：1  

赵玉龙  刘志飞 《地球科学进展》2007,22(4):341-349

古新世—始新世最热事件（PETM, Paleocene Eocene Thermal Maximum）是发生在古新世—始新世交界时的一次全球性的气候突变事件。它造成了大洋环流模式的突然倒转和海水盐度、大气湿度的迅速上升。海洋表层生态系统和陆地生态系统生产力迅速上升，许多属种的植物、动物、微生物生活范围向高纬区扩大；大洋底栖微生物发生集群灭绝。现代哺乳动物的主要属种（灵长类、奇蹄类及偶蹄类）产生，哺乳动物演化进程发生重大改变。地球表层碳循环系统发生不同程度的碳同位素负偏移，全球碳循环系统发生大规模搅动。对于PETM的触发机制，主流的观点认为是海底天然气水合物突然释放造成巨量甲烷迅速进入表层系统引发的碳循环系统内部反馈。而对于甲烷释放的原因，又存在着减压释放和热释放两种解释；此外还有科学家用岩浆作用和地外星体撞击来解释PETM的发生。  相似文献   

Seismicity before and after the two great Sumatra earthquakes of 2004 and 2005     

Sławomir Jerzy Gibowicz  Wojciech Dębski 《Acta Geophysica》2006,54(4):343-360

The Harvard CMT catalogue contains 481 shallow earthquakes that occurred between 1 January 1977 and 30 November 2005 within a broad region defined by the geographical latitude from 3°S to 14°N and by the longitude from 91°E to 102°E. There are 230 events that occurred before the great earthquake of 26 December 2004. Their surface distribution is not uniform and the source area of the 2004 great event appears as an area of seismic quiescence with a radius of about 100 km. There are 186 events that occurred between the two great earthquakes of 26 December 2004 and 28 March 2005. Practically all of them are located to the northwest from the great earthquake of 2005, that in turn was followed by 63 events, mostly located to the southeast. The cumulative seismic moment from earthquakes before the occurrence of the great event of 2004 increased rather regularly with time, with sudden increase about twenty years and two years before the occurrence of the great event. The seismic moment of earthquakes between the two great events increased rapidly during the first ten-fifteen days, then flattened out and increased slowly with time. After the great event of 2005 the seismic moment shows quiet increase during some 115 days, then sudden jump, followed by very small activity till the end of our observations. From the spatial distribution of seismic moment of earthquakes that occurred before the great event of 2004 it follows that its largest release appeared to the southeast from the great event, around the rupture area of the great earthquake of 2005. The largest release of seismic moment from earthquakes between the two great events is observed in the vicinity of the 2004 event and further up to the north. The seismic moment from earthquakes that occurred after the great event of 2005 was mostly released in its vicinity and further down to the south.  相似文献   

A stochastic model of surface contaminant releases to support assessment of site contamination at a former industrial site     

R. Mackay  J.A. Morakinyo 《Stochastic Environmental Research and Risk Assessment (SERRA)》2006,20(3):213-222

An industrial site is usually contaminated by accidental (and occasionally intentional) releases of pollutants to the environment from various operations carried out on that site. Consequently, the pattern of contamination created during the life of the site depends in part, at least, on the pattern of operations. Thus, the assessment of the pattern of contamination over the site should be improved: if it is possible to identify the pattern of operations on the site, the duration of the different activities and the perceived likelihood of releases from the different operations. A stochastic model has been developed that can be used to simulate alternative realizations of contaminant releases (duration, extent and timing). The model employs release zones associated with particular activities or groups of activities on the site and the areas of each of the zones may be independent or overlapping. The period of activity in each zone is obtained from the site records, while the likelihood and extent of contamination in each zone is inferred from an analysis of the contamination data obtained by point sampling. The form of the model, the method of inference of the model parameter values from the site data and the application of the model to the study site are presented. The release model has been developed as part of a suite of stochastic models for site ground contamination analysis. The stochastic soil and transport models and the application of the integrated modelling system are described in separate papers.  相似文献